Not (colloquial): chẳng / chả
not (spoken, emphatic)
Pattern: [person] + chẳng / chả + [verb or adjective]
In Saigon: chẳng · In Hà Nội: chẳng; chả
Typed without accents: chang, cha
Chẳng means "not", like không, and sits in the same place, before the verb or adjective: Em chẳng hiểu gì hết. I don't understand a thing. It's stronger and more emotional than không, and often carries a shrug or a complaint.
In Saigon, không is the everyday word. Chẳng comes up for emphasis, above all in set phrases: chẳng ai (nobody at all), chẳng có gì (nothing at all), chẳng bao giờ (never ever). You'll also meet it a lot in songs, books and writing. In Hà Nội, chẳng and its short form chả are ordinary in casual talk: Chả biết. Dunno.
Chẳng doesn't work as a one-word answer. To say "no", use không, or in the South dạ, không. And like không, it doesn't go straight before là: "isn't" with a noun is chẳng phải.
While you're learning, keep không for your own sentences, learn to recognise chẳng and chả, and use chẳng when you want to sound a little exasperated.
Examples
Highlighted words are what Saigon and Hà Nội say differently.
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Saigon
Em chẳng hiểu gì hết.
Hà Nội
Em chẳng hiểu gì cả.
I don't understand a thing.
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Chẳng ai nói với em.
Nobody told me.
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Không sao, chẳng có gì đâu.
Don't worry, it's nothing.
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Saigon
Anh ấy chẳng bao giờ đi trễ.
Hà Nội
Anh ấy chả bao giờ đi muộn.
He's never late, ever.